CLUSTER UNIVERSITY OF JAMMU
SYLLABUS – SEMESTER 1st (CBCS) –CHEMISTRY
(DISCIPLINE SPECIFIC CORE)
COURSE CODE : 1CHMTC0101 Pag
(EXAMINATION TO BE HELD IN 2017, 2018 AND 2019)
TITLE: ATOMIC STRUCTURE, BONDING, GENERAL ORGANIC
CHEMISTRY & ALIPHATIC HYDROCARBONS
COURSE CODE : 1CHMTC0101 CREDITS : 04
DURATION OF EXAMINATION TOTAL: 100 Marks
MINOR TEST : 01 Hour MINOR TEST: 20 Marks
MAJOR TEST : 2.5 Hours MAJOR TEST: 80 Marks
UNIT-1: Atomic Structure (12 HOURS)
Introduction of Quantum mechanics. Time independent Schrodinger equation and meaning of
various terms in it. Significance of ψ and ψ2, Schrödinger equation for hydrogen atom. Radial
and angular parts of the hydogenic wavefunctions (atomic orbitals) Radial and angular wave
function probability distribution curves of 1s, 2s, 2p and 3d orbitals. Quantum numbers and their
significance. Rules for filling electrons in various orbitals, Electronic configurations of the
atoms. Stability of half-filled and completely filled orbitals, concept of exchange energy.
UNIT-2: Chemical Bonding and Molecular Structure (12 HOURS)
Ionic Bonding: General characteristics of ionic bonding. Energy considerations in ionic bonding,
lattice energy and solvation energy and their importance in the context of stability and solubility
of ionic compounds. Born-Haber cycle and its applications, polarizing power and polarizability.
Fajan’s rules, ionic character in covalent compounds, bond moment, dipole moment and
percentage ionic character.
Covalent bonding: VB Approach: Shapes of some inorganic molecules and ions on the basis of
VSEPR and hybridization with suitable examples of linear, trigonal planar, square planar,
tetrahedral, trigonal bipyramidal and octahedral arrangements.
MO Approach: Rules for the LCAO method, bonding and antibonding MO treatment of
homonuclear diatomic molecules (H2, B2, C2, N2, O2, F2 and their ions) and heteronuclear
diatomic molecules such as CO, NO and NO+. Comparison of VB and MO approaches
UNIT-3: Bio-Inorganic Chemistry (12 HOURS)
A brief introduction to bio-inorganic chemistry. Role of metal ions present in biological
systems with special reference to Na+, K+ and Mg2+ ions: Na/K pump; Role of Mg2+ ions in
energy production and chlorophyll. Role of Ca2+ in blood clotting and structural role (bones).
Structure and importance of haemoglobin & myoglobin
UNIT-4: Fundamentals of Organic Chemistry & Stereochemistry (12 HOURS)
Fundamentals of Organic Chemistry: Physical Effects, Electronic Displacements: Inductive
Effect, Electromeric Effect, Resonance and Hyperconjugation. Nucleophiles and electrophiles.
Reactive Intermediates: Carbocations, Carbanions and free radicals.
Stereochemistry: Conformations with respect to ethane, butane and cyclohexane. Interconversion
of Wedge Formula, Newmann, Sawhorse and Fischer representations. Symmetry Elements
Concept of chirality (upto two carbon atoms). Configuration: Geometrical and Optical
isomerism; (Enantiomerism, Diastereomerism and Meso compounds). CIP Rules: R/ S (for upto
2 chiral carbon atoms) and E / Z Nomenclature (for upto two C=C systems).
UNIT-5: Aliphatic Hydrocarbons (12 HOURS)
Functional group approach for the following reactions (nomenclature, preparations & reactions)
to be studied in context to their structure.
Alkanes: Preparation: Catalytic hydrogenation, Wurtz reaction, Kolbe’s synthesis, from
Grignard reagent. Reactions: Free radical Substitution: Halogenation.
Alkenes: Preparation: Elimination reactions: Dehydration of alcohols and dehydrohalogenation
of alkyl halides (Saytzeff’s rule); cis-alkenes (Partial catalytic hydrogenation) and trans alkenes
(Birch reduction). Reactions: cis-addition (alk. KMnO4) and trans-addition (bromine), Addition
of HX (Markownikoff’s and anti-Markownikoff’s addition), Hydration, Ozonolysis,
Hydroboration-oxidation.
Alkynes: Preparation: Acetylene from CaC2 and conversion into higher alkynes; by
dehalogenation of tetra halides and dehydrohalogenation of vicinal-dihalides.
Reactions: formation of metal acetylides, addition of bromine and alkaline KMnO4, ozonolysis
and oxidation with hot alk. KMnO4.
Reference Books:
1. Lee, J.D. Concise Inorganic Chemistry ELBS, 1991.
2. Cotton, F.A., Wilkinson, G. & Gaus, P.L. Basic Inorganic Chemistry, 3rd ed., Wiley.
3. Douglas, B.E., McDaniel, D.H. & Alexander, J.J. Concepts and Models in Inorganic
Chemistry, John Wiley & Sons.
4. Huheey, J.E., Keiter, E.A., Keiter, R.L. & Medhi, O.K. Inorganic Chemistry:Principles
of Structure and Reactivity, Pearson Education India, 2006.
5. Graham Solomon, T.W., Fryhle, C.B. & Dnyder, S.A. Organic Chemistry, John Wiley &
Sons (2014).
6. McMurry, J.E. Fundamentals of Organic Chemistry, 7th Ed. Cengage Learning India
Edition, 2013.
7. Sykes, P. A Guidebook to Mechanism in Organic Chemistry, Orient Longman, New
Delhi (1988).
8. Eliel, E.L. Stereochemistry of Carbon Compounds, Tata McGraw Hill education, 2000.
9. Kalsi, P.S. Stereochemistry of Carbon Compounds, Tata McGraw Hill education, 2000.
10. Morrison, R.T. & Boyd, R.N. Organic Chemistry, Pearson, 2010.
11. Bahl, A. & Bahl, B.S. Advanced Organic Chemistry, S. Chand, 2010.
INSTRUCTIONS FOR PAPER SETTERS AND CANDIDATES:
1. The question paper for Semester End Examination will consist of two parts:
a) Part A will comprise of short answer /objective type questions of 16 marks (five
questions of 2 marks and six questions of 1 mark each) covering all five units.
b) Part B will comprise of eight questions of 16 marks each with two questions each from
II, III, IV and V units. The students will have to attempt four questions selecting one
question from each unit. Each question of 16 marks will have two parts: (i) long answer
question of 12 marks (ii) short answer question/numerical problem of 4 marks each. The
duration of the examination will be 2.5 hours.
2. The Minor Test will be held for unit I of the syllabus. It will comprise of two parts:
a) Part A consists of three long answer questions of 5 marks each and students will have to
attempt any two.
b) Part B consists of seven short answer questions of 2 marks each and students will have
to attempt any five.
SYLLABUS – SEMESTER 1st (CBCS) –CHEMISTRY
(DISCIPLINE SPECIFIC CORE)
COURSE CODE : 1CHMTC0101 Pag
(EXAMINATION TO BE HELD IN 2017, 2018 AND 2019)
TITLE: ATOMIC STRUCTURE, BONDING, GENERAL ORGANIC
CHEMISTRY & ALIPHATIC HYDROCARBONS
COURSE CODE : 1CHMTC0101 CREDITS : 04
DURATION OF EXAMINATION TOTAL: 100 Marks
MINOR TEST : 01 Hour MINOR TEST: 20 Marks
MAJOR TEST : 2.5 Hours MAJOR TEST: 80 Marks
UNIT-1: Atomic Structure (12 HOURS)
Introduction of Quantum mechanics. Time independent Schrodinger equation and meaning of
various terms in it. Significance of ψ and ψ2, Schrödinger equation for hydrogen atom. Radial
and angular parts of the hydogenic wavefunctions (atomic orbitals) Radial and angular wave
function probability distribution curves of 1s, 2s, 2p and 3d orbitals. Quantum numbers and their
significance. Rules for filling electrons in various orbitals, Electronic configurations of the
atoms. Stability of half-filled and completely filled orbitals, concept of exchange energy.
UNIT-2: Chemical Bonding and Molecular Structure (12 HOURS)
Ionic Bonding: General characteristics of ionic bonding. Energy considerations in ionic bonding,
lattice energy and solvation energy and their importance in the context of stability and solubility
of ionic compounds. Born-Haber cycle and its applications, polarizing power and polarizability.
Fajan’s rules, ionic character in covalent compounds, bond moment, dipole moment and
percentage ionic character.
Covalent bonding: VB Approach: Shapes of some inorganic molecules and ions on the basis of
VSEPR and hybridization with suitable examples of linear, trigonal planar, square planar,
tetrahedral, trigonal bipyramidal and octahedral arrangements.
MO Approach: Rules for the LCAO method, bonding and antibonding MO treatment of
homonuclear diatomic molecules (H2, B2, C2, N2, O2, F2 and their ions) and heteronuclear
diatomic molecules such as CO, NO and NO+. Comparison of VB and MO approaches
UNIT-3: Bio-Inorganic Chemistry (12 HOURS)
A brief introduction to bio-inorganic chemistry. Role of metal ions present in biological
systems with special reference to Na+, K+ and Mg2+ ions: Na/K pump; Role of Mg2+ ions in
energy production and chlorophyll. Role of Ca2+ in blood clotting and structural role (bones).
Structure and importance of haemoglobin & myoglobin
UNIT-4: Fundamentals of Organic Chemistry & Stereochemistry (12 HOURS)
Fundamentals of Organic Chemistry: Physical Effects, Electronic Displacements: Inductive
Effect, Electromeric Effect, Resonance and Hyperconjugation. Nucleophiles and electrophiles.
Reactive Intermediates: Carbocations, Carbanions and free radicals.
Stereochemistry: Conformations with respect to ethane, butane and cyclohexane. Interconversion
of Wedge Formula, Newmann, Sawhorse and Fischer representations. Symmetry Elements
Concept of chirality (upto two carbon atoms). Configuration: Geometrical and Optical
isomerism; (Enantiomerism, Diastereomerism and Meso compounds). CIP Rules: R/ S (for upto
2 chiral carbon atoms) and E / Z Nomenclature (for upto two C=C systems).
UNIT-5: Aliphatic Hydrocarbons (12 HOURS)
Functional group approach for the following reactions (nomenclature, preparations & reactions)
to be studied in context to their structure.
Alkanes: Preparation: Catalytic hydrogenation, Wurtz reaction, Kolbe’s synthesis, from
Grignard reagent. Reactions: Free radical Substitution: Halogenation.
Alkenes: Preparation: Elimination reactions: Dehydration of alcohols and dehydrohalogenation
of alkyl halides (Saytzeff’s rule); cis-alkenes (Partial catalytic hydrogenation) and trans alkenes
(Birch reduction). Reactions: cis-addition (alk. KMnO4) and trans-addition (bromine), Addition
of HX (Markownikoff’s and anti-Markownikoff’s addition), Hydration, Ozonolysis,
Hydroboration-oxidation.
Alkynes: Preparation: Acetylene from CaC2 and conversion into higher alkynes; by
dehalogenation of tetra halides and dehydrohalogenation of vicinal-dihalides.
Reactions: formation of metal acetylides, addition of bromine and alkaline KMnO4, ozonolysis
and oxidation with hot alk. KMnO4.
Reference Books:
1. Lee, J.D. Concise Inorganic Chemistry ELBS, 1991.
2. Cotton, F.A., Wilkinson, G. & Gaus, P.L. Basic Inorganic Chemistry, 3rd ed., Wiley.
3. Douglas, B.E., McDaniel, D.H. & Alexander, J.J. Concepts and Models in Inorganic
Chemistry, John Wiley & Sons.
4. Huheey, J.E., Keiter, E.A., Keiter, R.L. & Medhi, O.K. Inorganic Chemistry:Principles
of Structure and Reactivity, Pearson Education India, 2006.
5. Graham Solomon, T.W., Fryhle, C.B. & Dnyder, S.A. Organic Chemistry, John Wiley &
Sons (2014).
6. McMurry, J.E. Fundamentals of Organic Chemistry, 7th Ed. Cengage Learning India
Edition, 2013.
7. Sykes, P. A Guidebook to Mechanism in Organic Chemistry, Orient Longman, New
Delhi (1988).
8. Eliel, E.L. Stereochemistry of Carbon Compounds, Tata McGraw Hill education, 2000.
9. Kalsi, P.S. Stereochemistry of Carbon Compounds, Tata McGraw Hill education, 2000.
10. Morrison, R.T. & Boyd, R.N. Organic Chemistry, Pearson, 2010.
11. Bahl, A. & Bahl, B.S. Advanced Organic Chemistry, S. Chand, 2010.
INSTRUCTIONS FOR PAPER SETTERS AND CANDIDATES:
1. The question paper for Semester End Examination will consist of two parts:
a) Part A will comprise of short answer /objective type questions of 16 marks (five
questions of 2 marks and six questions of 1 mark each) covering all five units.
b) Part B will comprise of eight questions of 16 marks each with two questions each from
II, III, IV and V units. The students will have to attempt four questions selecting one
question from each unit. Each question of 16 marks will have two parts: (i) long answer
question of 12 marks (ii) short answer question/numerical problem of 4 marks each. The
duration of the examination will be 2.5 hours.
2. The Minor Test will be held for unit I of the syllabus. It will comprise of two parts:
a) Part A consists of three long answer questions of 5 marks each and students will have to
attempt any two.
b) Part B consists of seven short answer questions of 2 marks each and students will have
to attempt any five.
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